Химия свойства элементов

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Общие сведения и методы получения

Кобальт (Со) — тяжелый металл серебристого цвета с розоватым от-ливом. Оксид кобальта известен человечеству с незапамятных времен. Он применялся в Древнем Египте, Вавилоне, Китае для окрашивания стекол и эмалей в синий цвет. В 1735 г. шведский химик Брандт по­лучил металл, который назвал «корольком кобольда». Вскоре это на­звание было заменено на «кобольт», а затем —иа «кобальт».


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Рений ( Re ) в периодической системе располагается в VII А группе 6-го длинного периода.

В компактном состоянии имеет серовато-белый цвет, в диспергиро­ванном — черный.


Общие сведения и методы получения

Технеций (Тс) получил свое название от греческого слова «техникос», что означает искусственный. В периодической системе элементов распо­ложен в VIIA группе и 5-ом длинном периоде. В компактном состоя­нии имеет серебристо-серый цвет. Технеций — радиоактивный элемент. Существование технеция было предсказано Д. И. Менделеевым в 1870 г., а открыли этот элемент в 1937 г. Псрье и Сегрэ (Палермо).


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Марганец (Мп)—металл серебристо-белого цвета в компактном со­стоянии н светло-серого — в диспергированном. Марганец открыт К. Шееле в 1774 г. Содержание его в земной коре составляет 9*10 "2% (по массе). Наиболее распространенные минералы марганца — пиролю­зит и псиломелан.

Получают марганец восстановлением его оксидов кремнием в элек« тропечах, электролизом раствором MnS 04 и другими методами.

Физические свойства


Общие сведения и методы получения

Астат ( At ) — радиоактивный элемент; при нормальных условиях пред­ставляет собой черно-синие кристаллы. В природе встречается очень редко. Впервые его удалось обнаружить среди продуктов естественного радиоактивного распада радона, ничтожные количества обнаружены в продуктах распада урана и тория.

Приблизительные подсчеты показывают, что в двадцатикилометро­вой толще земной коры содержится примерно 30 г астата. В весомых количествам он не выделен.


Общие сведения и методы получения

Бром (Вг) —красио-бурая жидкость с резким неприятным запахом, от­носится к галогенам.

Бром открыт в 1826 г. во Франции химиком А. Ж. Баларом при изу­чении рассолов средиземноморских соляных промыслов; название эле­мента связано с его неприятным запахом (от греческого «бромос» — зловонный).

Из-за высокой химической активности в свободном виде не встреча­ется, находится в виде бромидов в морской воде, в водах соляных озер, нефтяных буровых скважин, в земной коре в верхних слоях залежей по­варенной соли.


Общие сведения и методы получения

Хлор (С1) — в свободном состоянии при нормальных условиях двухатом­ный газ С12 желто-зеленого цвета, относится к галогенам. Впервые хлор был получен в 1774 г. в Швеции Шееле взаимодействием соляной кисло, ты с пиролюзитом Мп02. Однако только в 1810 г. Дэви установил, что хлор — элемент и назвал его Chlorine (от греческого Chloros — желто-зеленый).

В 1812 г. Гей-Люссак предложил для этого элемента название хлор. В жидком виде был впервые получен в 1823 г. Фарадеем.